Scientists Were Wrong – Tiny Crystals Reveal That the Moon Is Millions of Years Older Than Previously Thought

Scientists from Northwestern University contributed to the analysis of lunar samples that were collected by astronauts during the Apollo 17 mission.

By analyzing tiny crystals from the Moon, collected during the Apollo 17 mission in 1972, scientists have revised the estimated age of the Moon. Previously thought to be 4.425 billion years old, the new analysis indicates it is around 4.46 billion years old, making it 40 million years older than earlier estimates.

Led by researchers at the Field Museum and the University of GlasgowLocated in Glasgow, Scotland, the University of Glasgow is a public research university that was founded in 1451 making it the fourth-oldest university in the English-speaking world. As a research-intensive university, it is a member of the Russell Group, Universitas 21, and the Guild of European Research-Intensive Universities. ” data-gt-translate-attributes=”[{“attribute”:”data-cmtooltip”, “format”:”html”}]”>University of Glasgow, the study was made possible by Northwestern UniversityEstablished in 1851, Northwestern University (NU) is a private research university based in Evanston, Illinois, United States. Northwestern is known for its McCormick School of Engineering and Applied Science, Kellogg School of Management, Feinberg School of Medicine, Pritzker School of Law, Bienen School of Music, and Medill School of Journalism. ” data-gt-translate-attributes=”[{“attribute”:”data-cmtooltip”, “format”:”html”}]”>Northwestern University’s atomAn atom is the smallest component of an element. It is made up of protons and neutrons within the nucleus, and electrons circling the nucleus.” data-gt-translate-attributes=”[{“attribute”:”data-cmtooltip”, “format”:”html”}]”>atom-probe tomography facility, which “nailed down” the age of the oldest crystal in the sample. By revealing the age of these telltale zircon crystals — found hidden within dust collected from the Moon — researchers were able to piece together the timeline of the Moon’s formation.

The study was recently published in the journal Geochemical Perspectives Letters.

Technological Evolution in Space Studies

“This study is a testament to immense technological progress we have made since 1972 when the last manned Moon mission returned to Earth,” said Northwestern’s Dieter Isheim, who co-authored the study. “These samples were brought to Earth half-a-century ago, but only today do we have the necessary tools to perform microanalysis at the requisite level, including atom-probe tomography.”

A lunar zircon grain under a microscope. Credit: Jennika Greer

The atom-by-atom analysis enabled researchers to count how many atoms in the zircon crystals have undergone radioactive decay. When an atom undergoes decay, it sheds protons and neutrons to transform into different elements. Uranium, for example, decays into lead. Because scientists have established how long it takes for this process to unfold, they can assess the age of a sample by looking at the proportion of uranium and lead atoms.

“Radiometric dating works a little bit like an hourglass,” said the Field Museum’s Philipp Heck, the study’s senior author. “In an hourglass, sand flows from one glass bulb to another, with the passage of time indicated by the accumulation of sand in the lower bulb. Radiometric dating works similarly by counting the number of parent atoms and the number of daughter atoms they have transformed to. The passage of time can then be calculated because the transformation rate is known.”

Isheim is a research associate professor of materials science and engineering at Northwestern’s McCormick School of Engineering and manager of Northwestern’s Center for Atom-Probe Tomography (NUCAPT). David Seidman, the Walter P. Murphy Professor Emeritus of Materials Science and Engineering at McCormick and founding director of NUCAPT, also co-authored the study. Heck is the Field Museum’s Robert A. Pritzker Curator for Meteorites and Polar Studies, senior director of the Negaunee Interactive Research Center and professor at the University of ChicagoFounded in 1890, the University of Chicago (UChicago, U of C, or Chicago) is a private research university in Chicago, Illinois. Located on a 217-acre campus in Chicago's Hyde Park neighborhood, near Lake Michigan, the school holds top-ten positions in various national and international rankings. UChicago is also well known for its professional schools: Pritzker School of Medicine, Booth School of Business, Law School, School of Social Service Administration, Harris School of Public Policy Studies, Divinity School and the Graham School of Continuing Liberal and Professional Studies, and Pritzker School of Molecular Engineering.” data-gt-translate-attributes=”[{“attribute”:”data-cmtooltip”, “format”:”html”}]”>University of Chicago. Jennika Greer, a research associate professor at the University of Glasgow, is the study’s lead author. When the research began, she was a Ph.D. candidate in Heck’s laboratory.

Lead author Jennika Greer working with the atom probe. Credit: Dieter Isheim, Northwestern

The Moon’s Formative Years

More than 4 billion years ago, when the solar system was still young and the Earth was still growing, a giant MarsMars is the second smallest planet in our solar system and the fourth planet from the sun. It is a dusty, cold, desert world with a very thin atmosphere. Iron oxide is prevalent in Mars' surface resulting in its reddish color and its nickname "The Red Planet." Mars' name comes from the Roman god of war.” data-gt-translate-attributes=”[{“attribute”:”data-cmtooltip”, “format”:”html”}]”>Mars-sized object crashed into the Earth. A colossal hunk broke off Earth to form the Moon, and the energy of the impact melted the rock that eventually became the Moon’s surface.

“When the surface was molten like that, zircon crystals couldn’t form and survive,” Heck said. “So, any crystals on the Moon’s surface must have formed after this lunar magma ocean cooled. Otherwise, they would have been melted and their chemical signatures would be erased.”

Because the crystals must have formed after the magma ocean cooled, determining the age of the zircon crystals would reveal the minimum possible age of the Moon. But, to pinpoint the maximum possible age of the Moon, researchers turned to Northwestern’s atom-probe tomography instruments.

“In atom-probe tomography, we start by sharpening a piece of the lunar sample into a very sharp tip, using a focused ion beam microscope, almost like a very fancy pencil sharpener,” Greer said. “Then, we use UV lasers to evaporate atoms from the surface of that tip. The atoms travel through a mass spectrometer, and how fast they move tells us how heavy they are, which in turn tells us what they’re made of.”

After determining the materials in the sample and performing radiometric dating, the researchers concluded that the oldest crystals are about 4.46 billion years old. That means the Moon must be at least that old.

It’s important to know when the Moon formed, Heck said, because “the Moon is an important partner in our planetary system. It stabilizes the Earth’s rotational axis. It’s the reason there are 24 hours in a day. It’s the reason we have tides. Without the Moon, life on Earth would look different. It’s a part of our natural system that we want to better understand, and our study provides a tiny puzzle piece in that whole picture.”

Reference: “4.46 Ga zircons anchor chronology of lunar magma ocean” by J. Greer, B. Zhang, D. Isheim, D.N. Seidman, A. Bouvier and P.R. Heck, 23 October 2023, Geochemical Perspectives Letters.
DOI: 10.7185/geochemlet.2334

The study was supported by NASAEstablished in 1958, the National Aeronautics and Space Administration (NASA) is an independent agency of the United States Federal Government that succeeded the National Advisory Committee for Aeronautics (NACA). It is responsible for the civilian space program, as well as aeronautics and aerospace research. Its vision is "To discover and expand knowledge for the benefit of humanity." Its core values are "safety, integrity, teamwork, excellence, and inclusion." NASA conducts research, develops technology and launches missions to explore and study Earth, the solar system, and the universe beyond. It also works to advance the state of knowledge in a wide range of scientific fields, including Earth and space science, planetary science, astrophysics, and heliophysics, and it collaborates with private companies and international partners to achieve its goals.” data-gt-translate-attributes=”[{“attribute”:”data-cmtooltip”, “format”:”html”}]”>NASA and the Field Museum’s Women’s Board Women in Science Graduate Fellowship. NUCAPT is supported by the National Science Foundation, the Office of Naval Research and the Paula M. Trienens Institute for Sustainability and Energy.